Expeditious, mechanochemical synthesis of BODIPY dyes

نویسندگان

  • Laramie P Jameson
  • Sergei V Dzyuba
چکیده

BODIPY dyes have been synthesized under solvent-free or essentially solvent-free conditions, within about 5 minutes in an open-to-air setup by using a pestle and mortar, with yields that are comparable to those obtained via traditional routes that typically require reaction times of several hours to days.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

One-pot efficient synthesis of dimeric, trimeric, and tetrameric BODIPY dyes for panchromatic absorptionw

4,4-Difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) dyes have received an upsurge of interest because they possess a variety of distinctive and desirable properties such as high absorption coefficients, narrow absorption and emission bands, good stability, excellent emission quantum yields, and have promising applications in supramolecular fluorescent gels, solar cells, sensing and imaging. A s...

متن کامل

A versatile, modular synthesis of monofunctionalized BODIPY dyes.

A careful choice of the pyrrole building blocks allows the synthesis of a wide range of monohalogenated BODIPY dyes with excellent reactivity in palladium catalyzed coupling reactions.

متن کامل

A new synthesis of symmetric boraindacene (BODIPY) dyes.

BODIPY dyes were synthesized from pyrrole-2-carbaldehyde derivatives in high yields; this constitutes a new approach to this dye framework.

متن کامل

Acetylene functionalized BODIPY dyes and their application in the synthesis of activity based proteasome probes.

The synthesis of three acetylene functionalized BODIPY dyes is described. These dyes are used to fluorescently modify an azido functionalized epoxomicin analogue employing the Huisgen 1,3-dipolar cycloaddition, resulting in a panel of fluorescent epoxomicin derived proteasome probes.

متن کامل

Solid-phase synthesis of BODIPY dyes and development of an immunoglobulin fluorescent sensor.

The diversification of the BODIPY scaffold has been hindered by its controversial adaptability to solid-phase chemistry. Herein we report the first solid-phase synthesis of a BODIPY library in high purities. We screened the library against a set of proteins, identified an immunoglobulin fluorescent sensor (Ig Orange) and confirmed its binding by SPR experiments.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 9  شماره 

صفحات  -

تاریخ انتشار 2013